How Industrial RO Systems Integrate EDI or Mixed-Bed Ion Exchange for Ultrapure Water Production| Insights by AQUALITEK

Monday, 10/27/2025

Discover how industrial RO systems use EDI (electrodeionization) or mixed-bed ion exchange as polishing steps to produce ultrapure water, and understand the key design considerations for reliable water quality performance.

RO + EDI / Mixed-Bed: The Ultimate Solution for Ultrapure Water

Industrial reverse osmosis (RO) systems are widely used to remove most dissolved ions from raw water. However, RO alone cannot achieve the extremely low conductivity requirements needed for ultrapure water applications, such as:

✅ Electronics & semiconductor manufacturing
✅ Power plant boiler feedwater
✅ Pharmaceutical & biotech production
✅ Precision chemical processing

To reach resistivity > 15–18 MΩ·cm, additional polishing purification is required:

➡️ EDI (Electrodeionization)
➡️ Mixed-bed ion exchange systems (MBIX/MB resin)

These technologies are integrated after RO to remove trace ions, silica, and TOC.

Typical Ultrapure Water Process Flow

Pretreatment → RO (1st Pass) → RO (2nd Pass) → EDI / Mixed Bed → Ultrapure Water Storage & Distribution

Why 2-pass RO?

✅ Greatly reduces TDS & CO₂
✅ Minimizes load on EDI/MBIX
✅ Improves overall system stability

Option 1: RO + EDI Integration (Continuous Polishing)

How EDI Works

Ion exchange resins + ion-selective membranes + DC electric field enable:

•Continuous ion removal

•No chemical regeneration required

•Constant production of ultrapure water

Advantages

✅ Continuous operation
✅ Lower operating cost (no chemicals)
✅ Stable product quality
✅ Small footprint, automation-friendly

Limitations

✖ Sensitive to feedwater quality
✖ CO₂, silica, hardness require strong pretreatment

Feedwater to EDI must have:

•Conductivity < 0.5–1.0 µS/cm

•Silica < 20–50 ppb

•Hardness ≈ 0 ppm

SDI < 1–2

Best for: Electronics & pharmaceuticals

Option 2: RO + Mixed-Bed Ion Exchange

Mixed-bed systems use cation & anion resin to exchange residual ions.

Advantages

✅ Excellent polishing capability
✅ Capable of achieving 18.2 MΩ·cm
✅ Better tolerance to feedwater fluctuations

Limitations

✖ Requires periodic chemical regeneration
✖ High labor & chemical handling cost
✖ Wastewater discharge & environmental control needed

Best for:

•Power plants with high peak water demands

•Facilities prioritizing highest polishing performance

EDI vs. Mixed-Bed — How to Choose?

Factor

EDI

Mixed-Bed

Operating Mode

Continuous

Batch

Regeneration

None

Required

Water Quality Stability

High

Very High

Operating Cost

Lower

Higher

Environmental Impact

Low

Chemical waste generated

Sensitivity to Feedwater

High

Medium

Common Use

Electronics, pharma

Power, critical ultrapure

Hybrid systems are sometimes used:
RO → EDI → Mixed Bed
(For guaranteed ultra-low ions)

Key Engineering Considerations

Design Factor

Recommendation

CO₂ Removal

Add degassing / membrane degasser after RO

Silica Control

Use pH adjustment + antiscalants

TOC Reduction

Activated carbon or UV TOC removal

Continuous Monitoring

Resistivity, pH, silica, sodium analyzers

Material Selection

UPVC, SS316L, or PVDF for purity piping

✅ Proper post-treatment is essential to avoid contamination and guarantee system reliability.

Final Recommendation

To produce consistent ultrapure water:

Use 2-pass RO + EDI as the preferred solution,
supplemented by polishing mixed-bed when extreme purity requirements or peak flow buffering are needed.

This combination enables:

✔ Reliable 18.2 MΩ·cm purity
✔ Low total cost of ownership
✔ Stable and automated operation

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